/etc/purple/prefs.xml is in pidgin-data 2.11.0-0+deb8u2.
This file is owned by root:root, with mode 0o644.
The actual contents of the file can be viewed below.
1 2 3 4 5 6 7 8 9 10 | <?xml version='1.0' encoding='UTF-8' ?>
<pref name='/'>
<pref name='pidgin'>
<pref name='browsers'>
<pref name='command' type='path' value='sensible-browser' />
<pref name='browser' type='string' value='custom' />
</pref>
</pref>
</pref>
</pref>
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