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/usr/share/avogadro/fragments/thiols/ethanethiol.cml is in avogadro-data 1.0.3-5.

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The actual contents of the file can be viewed below.

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<?xml version="1.0" encoding="UTF-8"?>
<molecule xmlns="http://www.xml-cml.org/schema"
          xmlns:cml="http://www.xml-cml.org/dict/cml"
          xmlns:units="http://www.xml-cml.org/units/units"
          xmlns:xsd="http://www.w3c.org/2001/XMLSchema"
          xmlns:iupac="http://www.iupac.org"
          id="CS_ethanethiol">
  <formula concise=" C 2 H 6 S 1 "/>
  <identifier convention="iupac:inchi" value="1/C2H6S/c1-2-3/h3H,2H2,1H3"/>
  <name convention="IUPAC">Ethanethiol</name>
  <atomArray>
    <atom id="a1" elementType="C" x3="0.943975" y3="-0.102603" z3="-0.075122"/>
    <atom id="a2" elementType="C" x3="-0.402355" y3="0.548541" z3="0.115926"/>
    <atom id="a3" elementType="S" x3="-1.812718" y3="-0.398119" z3="-0.534662"/>
    <atom id="a4" elementType="H" x3="1.014778" y3="-1.059179" z3="0.460340"/>
    <atom id="a5" elementType="H" x3="1.747916" y3="0.542792" z3="0.303883"/>
    <atom id="a6" elementType="H" x3="1.157340" y3="-0.302371" z3="-1.133870"/>
    <atom id="a7" elementType="H" x3="-0.444212" y3="1.516790" z3="-0.419752"/>
    <atom id="a8" elementType="H" x3="-0.560877" y3="0.783596" z3="1.184174"/>
    <atom id="a9" elementType="H" x3="-1.643847" y3="-1.529447" z3="0.099083"/>
  </atomArray>
  <bondArray>
    <bond atomRefs2="a1 a2" order="1"/>
    <bond atomRefs2="a2 a3" order="1"/>
    <bond atomRefs2="a1 a4" order="1"/>
    <bond atomRefs2="a1 a5" order="1"/>
    <bond atomRefs2="a1 a6" order="1"/>
    <bond atomRefs2="a2 a7" order="1"/>
    <bond atomRefs2="a2 a8" order="1"/>
    <bond atomRefs2="a3 a9" order="1"/>
  </bondArray>
  <propertyList>
    <property dictRef="cml:molwt" title="Molecular weight">
      <scalar dataType="xsd:double" dictRef="cml:molwt" units="units:g">62.1340</scalar>
    </property>
    <property dictRef="cml:monoisotopicwt" title="Monoisotopic weight">
      <scalar dataType="xsd:double" dictRef="cml:monoisotopicwt" units="units:g">62.0190212</scalar>
    </property>
    <property dictRef="cml:mp" title="Melting point">
      <scalar dataType="xsd:double" errorValue="2.0" dictRef="cml:mp" units="units:celsius">-146</scalar>
    </property>
    <property dictRef="cml:bp" title="Boiling point">
      <scalar dataType="xsd:double" errorValue="1.0" dictRef="cml:bp" units="units:celsius">35</scalar>
    </property>
  </propertyList>
</molecule>