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/usr/lib/x86_64-linux-gnu/pkgconfig/pangocairo.pc is in libpango1.0-dev 1.30.0-1.

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prefix=/usr
exec_prefix=${prefix}
libdir=/usr/lib/x86_64-linux-gnu
includedir=${prefix}/include

Name: Pango Cairo
Description: Cairo rendering support for Pango
Version: 1.30.0
Requires: pango cairo 
Libs: -L${libdir} -lpangocairo-1.0
Cflags: -I${includedir}/pango-1.0