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/usr/lib/s9fes/help/substitute is in scheme9 2010.11.13-2.

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S9 LIB  (substitute pair alist)  ==>  pair

Substitute objects in a given PAIR. The association list
ALIST contains the objects to be substituted as keys and
the corresponding substitutes as values.

(substitute '(* (+ 5 7) 9) '(((+ 5 7) . 12)))  ==>  (* 12 9)