/etc/libreoffice/psprint.conf is in libreoffice-common 1:6.0.3-0ubuntu1.
This file is owned by root:root, with mode 0o644.
The actual contents of the file can be viewed below.
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; This file is part of the LibreOffice project.
;
; This Source Code Form is subject to the terms of the Mozilla Public
; License, v. 2.0. If a copy of the MPL was not distributed with this
; file, You can obtain one at http://mozilla.org/MPL/2.0/.
;
; This file incorporates work covered by the following license notice:
;
; Licensed to the Apache Software Foundation (ASF) under one or more
; contributor license agreements. See the NOTICE file distributed
; with this work for additional information regarding copyright
; ownership. The ASF licenses this file to you under the Apache
; License, Version 2.0 (the "License"); you may not use this file
; except in compliance with the License. You may obtain a copy of
; the License at http://www.apache.org/licenses/LICENSE-2.0 .
;
[__Global_Printer_Defaults__]
; Copies: the default number of copies produced
; if key is absent the default is 1
; Copies=1
; Orientation: the default orientation of pages
; possible Values: Portrait, Landscape
; if key is absent the default is Portrait
; Orientation=Portrait
; Scale: the default scaling of output in percent
; if key is absent the default is 100
; Scale=100
; MarginAdjust: the default adjustment to driver margins in 1/100 mm
; MarginAdjust contains corrections for the driver defined margins
; the values are comma separated
; the order is: left,right,top,bottom
; if key is absent the default is 0,0,0,0
; MarginAdjust=0,0,0,0
; ColorDepth: the default colordepth of the device in bits
; possible values: 1, 8, 24
; if key is absent the default is 24
; ColorDepth=24
; ColorDevice: the default setting whether the device is color capable
; possible values: 0: driver setting, -1: grey scale, 1: color
; if key is absent the default is 0
; ColorDepth=0
; PSLevel: the default setting of the PostScript level of the output
; possible values: 0: driver setting, 1: level 1, 2: level2
; if key is absent the default is 0
; PSLevel=0
; PPD_PageSize: the default page size to use. If a specific printer does
; not support this page size its default is used instead.
; possible values: A0, A1, A2, A3, A4, A5, A6, B4, B5, B6,
; Legal, Letter, Executive, Statement, Tabloid,
; Ledger, AnsiC, AnsiD, ARCHA, ARCHB, ARCHC,
; ARCHD, ARCHE, EnvMonarch, EnvC4, EnvC5, EnvC6,
; Env10, EnvC65, Folio
; if key is absent the default value is driver specific
; PPD_PageSize=A4
[Generic Printer]
; for every printer a group with at least the keys
; "Printer" and "Command" is required
; Printer: contains the base name of the PPD and the Printer name separated by /
Printer=SGENPRT/Generic Printer
; DefaultPrinter: marks the default printer
DefaultPrinter=1
; Location: a user readable string that will be shown in the print dialog
Location=
; Comment: a user readable string that will be shown in the print dialog
Comment=
; Command: a command line that accepts PostScript as standard input (pipe)
; note: a shell will be started for the command
Command=
; QuickCommand: a command line that accepts PostScript as standard input (pipe)
; this command line will be used instead of the command line given in the
; "Command" key, if the user presses the direct print button. In this case
; no print dialog should be shown, neither form the printing applcation nor
; from the command line (example "kprinter --nodialog --stdin")
; note: a shell will be started for the command
;QuickCommand=
; Features: a string containing additional comma separated properties of a printer
; currently valid properties:
; fax for a Fax printer queue
; pdf=<dir> for a PDF printer where <dir> is the base directory for output files
; external_dialog to notify that the print command of a printer will show a dialog
; and therefore the application should not show its own dialog.
;Features=
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