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/usr/lib/pkgconfig/exiv2.pc is in libexiv2-dev 0.22-2.

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prefix=/usr
exec_prefix=${prefix}
libdir=${exec_prefix}/lib
includedir=${prefix}/include

Name: exiv2
Description: Image metadata library and tools
Version: 0.22
Libs: -L${libdir} -lexiv2 
Libs.private:    -lz  -lm -lexpat
Cflags: -I${includedir}