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        <a href="Scientific.Physics-module.html">Package&nbsp;Physics</a> ::
        Module&nbsp;Potential
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<!-- ==================== MODULE DESCRIPTION ==================== -->
<h1 class="epydoc">Module Potential</h1><p class="nomargin-top"></p>
<p>Potential energy functions with automatic gradient evaluation</p>
  <p>This module offers two strategies for automagically calculating the 
  gradients (and optionally force constants) of a potential energy function
  (or any other function of vectors, for that matter).  The more convenient
  strategy is to create an object of the class PotentialWithGradients. It 
  takes a regular Python function object defining the potential energy and 
  is itself a callable object returning the energy and its gradients with 
  respect to all arguments that are vectors.</p>
  <p>Example:</p>
<pre class="literalblock">
 &gt;&gt;&gt;def _harmonic(k,r1,r2):
 &gt;&gt;&gt;    dr = r2-r1
 &gt;&gt;&gt;    return k*dr*dr
 &gt;&gt;&gt;harmonic = PotentialWithGradients(_harmonic)
 &gt;&gt;&gt;energy, gradients = harmonic(1., Vector(0,3,1), Vector(1,2,0))
 &gt;&gt;&gt;print energy, gradients
</pre>
  <p>prints:</p>
<pre class="literalblock">
 &gt;&gt;&gt;3.0
 &gt;&gt;&gt;[Vector(-2.0,2.0,2.0), Vector(2.0,-2.0,-2.0)]
</pre>
  <p>The disadvantage of this procedure is that if one of the arguments is 
  a vector parameter, rather than a position, an unnecessary gradient will 
  be calculated. A more flexible method is to insert calls to two function 
  from this module into the definition of the energy function. The first, 
  DerivVectors(), is called to indicate which vectors correspond to 
  gradients, and the second, EnergyGradients(), extracts energy and 
  gradients from the result of the calculation. The above example is 
  therefore equivalent to:</p>
<pre class="literalblock">
 &gt;&gt;&gt;def harmonic(k, r1, r2):
 &gt;&gt;&gt;    r1, r2 = DerivVectors(r1, r2)
 &gt;&gt;&gt;    dr = r2-r1
 &gt;&gt;&gt;    e = k*dr*dr
 &gt;&gt;&gt;    return EnergyGradients(e,2)
</pre>
  <p>To include the force constant matrix, the above example has to be 
  modified as follows:</p>
<pre class="literalblock">
 &gt;&gt;&gt;def _harmonic(k,r1,r2):
 &gt;&gt;&gt;    dr = r2-r1
 &gt;&gt;&gt;    return k*dr*dr
 &gt;&gt;&gt;harmonic = PotentialWithGradientsAndForceConstants(_harmonic)
 &gt;&gt;&gt;energy, gradients, force_constants = harmonic(1.,Vector(0,3,1),Vector(1,2,0))
 &gt;&gt;&gt;print energy
 &gt;&gt;&gt;print gradients
 &gt;&gt;&gt;print force_constants
</pre>
  <p>The force constants are returned as a nested list representing a 
  matrix. This can easily be converted to an array for further processing 
  if the numerical extensions to Python are available.</p>

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