/etc/texmf/dvi2ps/lprdvi.conf is in dvi2ps 4.1j-3.
This file is owned by root:root, with mode 0o644.
The actual contents of the file can be viewed below.
1 2 3 4 5 6 7 | # logical printer name to printer spec and lpr option
# change lpXX and XXPRINTER, and add cases for more printers
lp LW16
lp1 RicohIPSiO
lp2 RicohIPSiO2 -h
lpXX XXPRINTER
* LW16
|