/usr/share/xfce4/helpers/pcmanfm.desktop is in libexo-helpers 0.6.2-4.
This file is owned by root:root, with mode 0o644.
The actual contents of the file can be viewed below.
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Version=1.0
Icon=pcmanfm
Type=X-XFCE-Helper
Name=PCMan File Manager
Name[ar]=PCMan مدير الملفات
Name[ast]=Xestor de ficheros PCMan
Name[bn]=PCMan ফাইল ম্যানেজার
Name[ca]=Gestor de fitxers PCMan
Name[cs]=Správce souborů PCMan
Name[da]=PCMan-filhåndtering
Name[de]=Dateimanager PCMan
Name[el]=Διαχειριστής αρχείων PCMan
Name[en_GB]=PCMan File Manager
Name[es]=PCMan File Manager
Name[eu]=PCM fitxategi kudeatzailea
Name[fi]=PCMan-tiedostonhallinta
Name[fr]=PCMan Gestionnaire de fichiers
Name[gl]=Xestor de ficheiros PCMan
Name[he]=מנהל הקבצים של PCMan
Name[hr]=PCMan upravitelj datotekama
Name[hu]=PCMan fájlkezelő
Name[id]=Manajer Berkas PCMan
Name[it]=PCMan File Manager
Name[ja]=PCMan File Manager
Name[kk]=PCMan файлдарды басқарушысы
Name[lv]=PCMan failu pārvaldnieks
Name[nb]=PCMan Filbehandler
Name[nl]=PCMan Bestandbeheerder
Name[pa]=PCMan ਫਾਇਲ ਮੈਨੇਜਰ
Name[pl]=PCMan File Manager
Name[pt]=Gestor de ficheiros PCMan
Name[pt_BR]=Gerenciador de arquivos PCManFM
Name[ro]=Managerul de fișiere PCMan
Name[ru]=PCMan File Manager
Name[sk]=PCMan správca súborov
Name[sv]=Filhanteraren PCMan
Name[tr]=PCMan Dosya Yöneticisi
Name[ug]=PCMan ھۆججەت باشقۇرغۇ
Name[uk]=Файловий менеджер PCMan
Name[zh_CN]=PCMan 文件管理器
Name[zh_TW]=PCMan 檔案管理員
StartupNotify=true
X-XFCE-Binaries=pcmanfm;
X-XFCE-Category=FileManager
X-XFCE-Commands=%B;
X-XFCE-CommandsWithParameter=%B "%s";
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