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/usr/share/gromacs/top/spce.itp is in gromacs-data 4.6.5-1build1.

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; This file is for backward compatibility only.
; Please directly include the spce.itp file from your force field directory.
#ifdef _FF_GROMACS
#include "gmx.ff/spce.itp"
#endif
#ifdef _FF_GROMOS96
#include "gromos43a1.ff/spce.itp"
#endif
#ifdef _FF_OPLS  
#include "oplsaa.ff/spce.itp"
#endif